BUTYL OXITOL (EGMBE)

Material Safety Datasheet CAS No 111-76-2
Date Issued: 2008/08/14
BUTYL OXITOL (EGMBE)
Company Details

Name Protea Chemicals - Cape Emergency Tel 082-490-5011
Address 54 Killarney Avenue Tel 021-550-8100
Killarney Gardens Fax 021-550-8180
Milnerton 7441
Email: rfyfe@proteachemicals.co.za

1.Product and Company Identification

Trade / Commercial Name BUTYL OXITOL (EGMBE)
Chemical Name 2-Butoxy ethanol
Formula C6H14O2
Chemical Family Glycol ether
Synonyms Butyl cellosolve; Dowanol EB; Butyl oxitol; Jeffersol EB; Ethylene glycol n-butyl ether
Un No 2810 Hazchem Code 2r
ERG No 153 EAC 26

2. Composition

Hazardous Components No

3. Hazards Identification

Main Hazard: poisonous
Flammability: Flammable limits in air : 1.1 - 10.6%
Chemical Hazard: can give off poisonous gases if diluted with water
Biological Hazard: not available
Reproductive Hazard: not available
Eye effects: eyes: causes irritation
Health effects - skin: causes irritation
Health effects - ingestion: poisonous ; grade 2
Health effects - inhalation: not available
Carcinogenicity: not available
Mutagenicity: not available
Neurotoxicity: not available

4. First Aid Measures

First Aid Skin Immediately remove contaminated clothing, including shoes.
Wash affected area with plenty of soap and water for at least 20 minutes.
First Aid Eyes Flush eyes with water for 15 minutes.
Hold eyelids open while washing.
First Aid Ingested Not applicable.
First Aid Inhalation IMMEDIATELY remove to fresh air.
If not breathing give artificial respiration.
If breathing of victim is difficult administer oxygen for a maximum period of one hour.

5. Fire Fighting Measures

Extinguishing media: Dry chemical, alcohol foam, carbon dioxide
Special hazards: Fire could produce irritating and poisonous gases.
Protective clothing: Self contained breathing apparatus and chemical protective clothing NB structural firefighter's protective clothing is not effective with this product

6. Accidental Release Measures

Full protective clothing including breathing apparatus
Dilute (substance may be washed to drain with a lot of water)
PRECAUTIONS:
Restrict access to area.
Provide adequate protective equipment and ventilation.
Remove sources of heat and flame.
Notify occupational and environmental authorities.
SPILL OR LEAK:
Do not touch spilled material.
Stop leak if you can do it without risk.
SMALL SPILLS:
Takeup with sand or other noncombustible absorbent material
and place into containers for later disposal.
SMALL DRY SPILLS: With clean shovel place material into clean,
dry container and cover; move container from spill area.
LARGE SPILLS:
Dike far ahead of liquid spill for later disposal.

7. Handling And Storage

Suitable material: stainless steel
Handling / storage precautions: Separation of at least 3m from corrosives.
Fire separation of 5m from flammable chemicals and oxidising agents.
Storage 10m apart from explosives, organic peroxides.

8. Exposure Controls/Personal Protection

Occupational Exposure Limits T W A OEL-RL SHORT TERM OEL-RL
-------------------- --------------------
PPMa) MG/M3b) PPMa) MG/M3b)
--------- --------- --------- ---------
25 120 - - SK
Controls The control measures appropriate for a particular worksite depend
on how this material is used and on the extent of exposure.
The best protection is to enclose operations and/or provide
local exhaust ventilation at the site of chemical release.
Use a non-sparking, grounded ventilation system separate from other
exhaust ventilation systems. Exhaust directly to the outside.
Supply sufficient replacement air to make up for air removed.
Have a safety shower/eye wash fountain readily available in the immediate work area
Personal Protection If engineering controls and work practices are not effective in
controlling this material, then wear suitable personal protection
equipment, including chemical safety goggles & face shield, boots,
imperious gloves, coveralls, & respiratory protection.
Have appropriate equipment available for use in emergencies.

9. Physical & Chemical Properties

Appearance: colourless,oily
Odour: mild rancid
pH: not available
Boiling point: 171,2C
Melting point: not available
Flash point: 61C
Flammability: yes
Autoflammability: Ignition temperature = 472F
Explosive properties: Attacks many metals , liberating hydrogen which forms explosive mixture with air
Oxidizing properties: no
Vapour pressure: not available
Density: 0.9
Solubility - water: Mixes easily
Solubility - solvent:
Solubility - coefficient:
Neurotoxicity:

10. Stability And Reactivity

Conditions to Avoid
Incompatible Materials oxidising agents, flammable and explosive material
Other

11. Toxicological Information

Acute Toxicity: ingestion,inhalation,skin contact,eye contact
Skin and eye contact: see above
Chronic toxicity: mutagecicity,carcinogenicity,reproduction
Carcinogenicity: probable
Mutagenicity: yes
Reproductive Hazards: yes

12. Ecological Information

No ecological problems are expected when the product is handled and used with due care.

13. Disposal Considerations

Disposal Method Product There are no uniform EC regulations for the disposal of chemicals or residues.
Chemical residues generally count as special waste.
The disposal of the latter is regulated in the EC member countries through corresponding laws and regulations.
We recommend that you contact the authorities in charge or approved
waste disposal companies which will advise you on how to dispose of special waste.
Disposal Method Packaging Disposal in accordance with local legal provisions.

14. Transport Information

UN No 2810 Hazchem Code 2r
ERG No 153 EAC 26
IMDG-Shipping Name BUTYL OXITOL
IMDG Code 6085.1 IMDG-Packaging Group III
Marine Pollutant Yes
Class Class: 6.1 Poison Group: III
Subsidiary Risks None

15. Regulatory Information

EEC Hazard Classification 6.1
Risk Phases Irritating to respiratory system
Safety Phases Avoid contact with skin and eyes
National Legislation

16. Other Information

Reason for Alteration: General update.

The information contained herein is based on the present state of our knowledge.
It characterizes the product with regard to the appropriate safety precautions.
It does not represent a guarantee of the properness of the product.

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All information is given in good faith but without guarantee in respect of accuracy & no responsibility is accepted for errors or omissions or the consequences thereof.