BAC 50

Material Safety Datasheet CAS No
Date Issued: 2008/08/14
BAC 50
Company Details

Name Protea Chemicals - Cape Emergency Tel 082-490-5011
Address 54 Killarney Avenue Tel 021-550-8100
Killarney Gardens Fax 021-550-8180
Milnerton 7441
Email: rfyfe@proteachemicals.co.za

1.Product and Company Identification

Trade / Commercial Name BAC 50
Chemical Name microbicide, liq, broad spectrum (5 chloro-2 methyl-4-isothiazolin-3-one, 2-methyl-4-isothiazolin-3-
Formula
Chemical Family Cationic Biocide/disinfectant
Synonyms
Un No 1760 Hazchem Code 3x
ERG No 154 EAC 60

2. Composition

Hazardous Components Approx. 50% benzalkonium chloride solution with chain lenght distribuion:
BAC 50 L: 100 % C12
BAC 50 M: 70 % C12 + 30 % C14
BAC 50 H: 40 % C12 + 50 % C14 + 10 % C16

3. Hazards Identification

Corrosive
Breathing vapours can cause serious lung injury.
If inhaled, could be harmful.
Irritant to eyes and skin.
Fire could produce irritating or poisonous gases.
Runoff from fire-control or dilution water could cause pollution.

4. First Aid Measures

First Aid Skin Flush body with plenty of water for at least 15 minutes.
Immerse frostbitten areas in warm water or apply warm water compresses to frozen parts.
Do not rub affected skin.
Immediately remove contaminated clothing, including shoes.
First Aid Eyes Flush eyes with water for 15 minutes.
Hold eyelids open while washing.
If pain persists, place 2-3 drops 1/2 % pontocaine solution in affected eye(s).
(ponotocaine is also known as "amethocaine", "tetracaine" and "pantocaine")
First Aid Ingested No specific treatment.
First Aid Inhalation If not breathing give artificial respiration.
If breathing of victim is difficult administer oxygen for a maximum period of one hour.

5. Fire Fighting Measures

Some of these materials may react violently with water.
SMALL FIRES: Dry chemical, CO2, Halon, water spray or standard foam.
LARGE FIRES: Water spray, fog or standard foam is recommended.
Move container from fire area if you can do it without risk.
Cool containers that are exposed to flames with water from the
side until well after the fire is out. Stay away from ends of tanks.
Keep unnecessary people away; isolate hazard area and deny entry.
Stay upwind; keep out of low areas.
Self-contained breathing apparatus (SCBA) and structural firefighter's
protective clothing will provide limited protection.

6. Accidental Release Measures

Full protective clothing including breathing apparatus
Contain (avoid spillage from entering drains or water courses)
PRECAUTIONS:
Restrict access to area.
Provide adequate protective equipment and ventilation.
Remove sources of heat and flame.
Notify occupational and environmental authorities.
SPILL OR LEAK:
Do not touch spilled material.
Stop leak if you can do it without risk.
SMALL SPILLS:
Takeup with sand or other noncombustible absorbent material
and place into containers for later disposal.
SMALL DRY SPILLS: With clean shovel place material into clean,
dry container and cover; move container from spill area.
LARGE SPILLS:
Dike far ahead of liquid spill for later disposal.

7. Handling And Storage

Separation of at least 3M from the following classes is recommended.
Flammable Liquids Flammable Solids
Spontaneously Combustibles Poison
Fire separation of at least 5M or 4Hr fire resistant wall
from the following classes is recommended.
Flammable Gases Dangerous When Wet
Oxidizing Agents Organic Peroxides
Storage in the same room or space is prohibited with the following classes:
The rooms or spaces should be at least 10M apart.
Explosives Radioactive

8. Exposure Controls/Personal Protection

Occupational Exposure Limits No Exposure Limits Established
Controls The control measures appropriate for a particular worksite depend
on how this material is used and on the extent of exposure.
The best protection is to enclose operations and/or provide
local exhaust ventilation at the site of chemical release.
Use a non-sparking, grounded ventilation system separate from other
exhaust ventilation systems. Exhaust directly to the outside.
Supply sufficient replacement air to make up for air removed.
Have a safety shower/eye wash fountain readily available in the immediate work area
Personal Protection If engineering controls and work practices are not effective in
controlling this material, then wear suitable personal protection
equipment, including chemical safety goggles & face shield, boots,
imperious gloves, coveralls, & respiratory protection.
Have appropriate equipment available for use in emergencies.

9. Physical & Chemical Properties

Clear - pale straw coloured liquid
Odour: characteristic
Density: approx. 0.98 g/cm3
Fully soluble in water, low molecular weight alcohols and ketones
Stable in the presence of light, pH range od 4 - 10 and 120 deg C

10. Stability And Reactivity

Conditions to Avoid extreme temperatures
Incompatible Materials
Other

11. Toxicological Information

Acute oral toxicity LD50: 200 - 2000 ppm (rat)

12. Ecological Information

No ecological problems are expected when the product is handled and used with due care.

13. Disposal Considerations

Disposal Method Product There are no uniform EC regulations for the disposal of chemicals or residues.
Chemical residues generally count as special waste.
The disposal of the latter is regulated in the EC member countries through corresponding laws and regulations.
We recommend that you contact the authorities in charge or approved
waste disposal companies which will advise you on how to dispose of special waste.
Disposal Method Packaging Disposal in accordance with local legal provisions.

14. Transport Information

UN No 1760 Hazchem Code 3x
ERG No 154 EAC 60
IMDG-Shipping Name BAC 50
IMDG Code 8 IMDG-Packaging Group III
Marine Pollutant Yes
Class Class: 8 Corrosive Group: I/II/III
Subsidiary Risks None

15. Regulatory Information

EEC Hazard Classification 8
Risk Phases R21/22 Harmful in contact with skin and if swallowed
R34 Causes burns
R50 Very toxix to aquatic organisms
Safety Phases S36/37/39 Wear suitable protective clothing, gloves and eye/face protection
S45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advise
S61 Avoid release to the environment: refer to special instructions
National Legislation

16. Other Information

Reason for Alteration: General update.

The information contained herein is based on the present state of our knowledge.
It characterizes the product with regard to the appropriate safety precautions.
It does not represent a guarantee of the properness of the product.

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All information is given in good faith but without guarantee in respect of accuracy & no responsibility is accepted for errors or omissions or the consequences thereof.